XANTHIC ANHYDRIDES - A NOVEL AND CONVENIENT SOURCE OF ALKOXYTHIOCARBONYL AND ALKYL RADICALS

被引：20

作者：

FORBES, J ^{[1
]}

ZARD, SZ ^{[1
]}

机构：

[1] ECOLE POLYTECH,CNRS,SYNTHESE ORGAN LAB,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON | 1993年 / 49卷 / 36期

关键词：

D O I：

10.1016/S0040-4020(01)88043-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Upon irradiation with visible light, xanthic anhydrides 14 undergo a chain reaction leading to xanthates 17 and involving beta-scission of the intermediate alkoxythiocarbonyl radical.

引用

页码：8257 / 8266

页数：10

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