XANTHIC ANHYDRIDES - A NOVEL AND CONVENIENT SOURCE OF ALKOXYTHIOCARBONYL AND ALKYL RADICALS

被引：20

作者：

FORBES, J ^{[1
]}

ZARD, SZ ^{[1
]}

机构：

[1] ECOLE POLYTECH,CNRS,SYNTHESE ORGAN LAB,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON | 1993年 / 49卷 / 36期

关键词：

D O I：

10.1016/S0040-4020(01)88043-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Upon irradiation with visible light, xanthic anhydrides 14 undergo a chain reaction leading to xanthates 17 and involving beta-scission of the intermediate alkoxythiocarbonyl radical.

引用

页码：8257 / 8266

页数：10

共 39 条

[31]

MINISCI F, 1990, SULFUR CENTERED REAC, P303

[32] STEROIDS AND SEX-HORMONES .262. THE RADICAL INDUCED STANNANE REDUCTION OF SELENOESTERS AND SELENOCARBONATES - A NEW METHOD FOR THE DEGRADATION OF CARBOXYLIC-ACIDS TO NOR-ALKANES AND FOR DEOXYGENATION OF ALCOHOLS TO ALKANES [J].

PFENNINGER, J ;

HEUBERGER, C ;

GRAF, W .

HELVETICA CHIMICA ACTA, 1980, 63 (08) :2328-2337

[33] NUCLEIC-ACID RELATED-COMPOUNDS .42. A GENERAL PROCEDURE FOR THE EFFICIENT DEOXYGENATION OF SECONDARY ALCOHOLS - REGIOSPECIFIC AND STEREOSELECTIVE CONVERSION OF RIBONUCLEOSIDES TO 2'-DEOXYNUCLEOSIDES [J].

ROBINS, MJ ;

WILSON, JS ;

HANSSKE, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (12) :4059-4065

[34] RATE CONSTANTS FOR THE DECARBOXYLATION OF THE TERT-BUTOXICARBONYL RADICAL AND CONCURRING RADICAL TERMINATIONS DIRECTLY OBTAINED BY KINETIC ELECTRON-SPIN-RESONANCE [J].

RUEGGE, D ;

FISCHER, H .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1986, 18 (02) :145-158

[35] PHOTOLYSIS OF SOME CARBOHYDRATE DITHIOBIS (THIOFORMATES) [J].

STOUT, EI ;

DOANE, WM ;

RUSSELL, CR ;

JONES, LB .

JOURNAL OF ORGANIC CHEMISTRY, 1975, 40 (09) :1331-1336

[36] A study of aliphatic polysulfides [J].

Twiss, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1927, 49 :491-494

[37] PEROXIDE-INDUCED ADDITIONS OF METHYL FORMATE TO OLEFINS [J].

URRY, WH ;

HUYSER, ES .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1953, 75 (19) :4876-4877

[38]

VOGEL AI, 1970, PRACTICAL ORGANIC CH, P499

[39]

Welde H., 1877, J PRAKT CHEM, V15, P43

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