SYNTHESIS AND NEW REACTIONS OF ALKYNYLCOBALT COMPLEXES - PREPARATION AND STRUCTURE OF [CO(ETA(2)ETA(1)-C6H4P(OET)(2)C(H)C(H)PH)(CO)(PPH(OET)(2))(2)]BPH(4)

被引：7

作者：

ALBERTIN, G ^{[1
]}

ANTONIUTTI, S ^{[1
]}

BACCHI, A ^{[1
]}

BORDIGNON, E ^{[1
]}

PELIZZI, G ^{[1
]}

机构：

[1] CNR,CTR STUDIO STRUTTURIST DIFFRATTOMETR,DIPARTIMENTO CHIM GEN & INORGAN,I-43100 PARMA,ITALY

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 09期

关键词：

D O I：

10.1021/om00009a016

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The alkynylcobalt complexes Co(C=CR)(CO){PPh(OEt)(2)}(3) (1) (R = Ph, p-tol) were prepared. Protonation reaction with HBF4 . Et(2)O or CF3SO3H allowed the synthesis of [Co{eta(2):eta(1)-C6H4P(OEt)(2)C(H)=C(H)R}(CO){PPh(OEt)(2)}(2)BPh(4) (2) derivatives, which were characterized crystallographically and spectroscopically. Oxidation of 1 with I-2 affording CoI2(C=CR)-(CO){PPh(OEt)(2))(2) was also tested.

引用

页码：4126 / 4131

页数：6

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