PREPARATION OF POLYANILINE FILMS DOPED WITH METHYLENE BLUE-BOUND NAFION AND THE ELECTROCHROMIC PROPERTIES OF THE RESULTING FILMS

被引：23

作者：

KUWABATA, S ^{[1
]}

MITSUI, K ^{[1
]}

YONEYAMA, H ^{[1
]}

机构：

[1] OSAKA UNIV,FAC ENGN,DEPT APPL CHEM,YAMADA KA 2-1,SUITA,OSAKA 565,JAPAN

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1990年 / 281卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(90)87032-F

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The preparation of polyaniline films doped with cationic methylene blue has been accomplished by the electro-oxidation of aniline in the presence of dissolved Nafion and methylene blue. The amount of methylene blue in the film could be varied by changing the relative concentration of methylene blue to Nafion in the deposition bath of polyaniline. The incorporation behaviour of methylene blue in polyaniline films is discussed in terms of the electrostatic binding of methylene blue with the sulphonate groups of Nation® in the deposition bath. The resulting films showed electrochemical responses of both polyaniline and methylene blue. © 1990.

引用

页码：97 / 107

页数：11

共 32 条

[11] ELECTROCHEMICAL-BEHAVIOR OF POLYANILINE IN WEAK ACID-SOLUTIONS [J].

HIRAI, T ;

KUWABATA, S ;

YONEYAMA, H .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :969-976

[12] POLYANILINE, A NOVEL CONDUCTING POLYMER - MORPHOLOGY AND CHEMISTRY OF ITS OXIDATION AND REDUCTION IN AQUEOUS-ELECTROLYTES [J].

HUANG, WS ;

HUMPHREY, BD ;

MACDIARMID, AG .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :2385-&

[13] RESEARCH ON CHEMICALLY MODIFIED ELECTRODES - CATALYTIC REDUCTION OF DIOXYGEN AT A COBALT PHTHALOCYANINE-DOPED POLYANILINE FILM ELECTRODE [J].

JIANG, RZ ;

DONG, SJ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1988, 246 (01) :101-117

[14]

KANEKO M, 1987, MAKROMOL CHEM-RAPID, V8, P179

[15] BASIC BEHAVIORS AND PROPERTIES OF THE ELECTRODEPOSITED POLYANILINE [J].

KITANI, A ;

IZUMI, J ;

YANO, J ;

HIROMOTO, Y ;

SASAKI, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (08) :2254-2257

[16] ECD MATERIALS FOR THE 3 PRIMARY COLORS DEVELOPED BY POLYANILINES [J].

KITANI, A ;

YANO, J ;

SASAKI, K .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1986, 209 (01) :227-232

[17] THE BINDING OF ORGANIC IONS BY PROTEINS [J].

KLOTZ, IM ;

WALKER, FM ;

PIVAN, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1946, 68 (08) :1486-1490

[18] POLYANILINE FILM-COATED ELECTRODES AS ELECTROCHROMIC DISPLAY DEVICES [J].

KOBAYASHI, T ;

YONEYAMA, H ;

TAMURA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 161 (02) :419-423

[19] ELECTROCHEMICAL REACTIONS CONCERNED WITH ELECTROCHROMISM OF POLYANILINE FILM-COATED ELECTRODES [J].

KOBAYASHI, T ;

YONEYAMA, H ;

TAMURA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1984, 177 (1-2) :281-291

[20] DIMERIZATION KINETICS OF METHYLENE-BLUE INCORPORATED IN A NAFION FILM [J].

KUWABATA, S ;

NAKAMURA, J ;

YONEYAMA, H .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1989, 261 (2B) :363-373

← 1 2 3 4 →