ALPHA,ALPHA-ALLO-TREHALOSE TRIHYDRATE

被引：6

作者：

LINDEN, A ^{[1
]}

LEE, CK ^{[1
]}

机构：

[1] NATL UNIV SINGAPORE,DEPT CHEM,SINGAPORE 0511,SINGAPORE

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1995年 / 51卷

关键词：

D O I：

10.1107/S0108270194012102

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The low-temperature X-ray structure of alpha,alpha-allo-trehalose trihydrate (alpha-D-allopyranosyl alpha-D-allopyranoside trihydrate, C12H22O11.3H(2)O) is reported. There are two conformationally similar, but symmetry-independent sugar molecules plus six water molecules in the asymmetric unit. The sugar molecules lack internal crystallographic symmetry because of the relative conformations of the hydroxymethyl substituents and the torsion angles about the glycosidic linkage. The pyranose rings have slightly distorted C-4(1) conformations. The sugar and water molecules are linked by many hydrogen bonds to form a complex three-dimensional network. The intramolecular O ... O contact distances are larger than those reported in a calcium complex of alpha,alpha-allo-trehalose.

引用

页码：1007 / 1012

页数：6

共 29 条

[1]

ANGYAL SJ, 1974, TETRAHEDRON, V30, P1695

[2] ANOMERIC BOND-CHARACTER IN PYRANOSE SUGARS [J].

BERMAN, HM ;

CHU, SSC ;

JEFFREY, GA .

SCIENCE, 1967, 157 (3796) :1576-&

[3]

Birch G. G., 1970, Journal of Food Technology, V5, P277, DOI 10.1016/S1078-3903(99)90053-8

[4] CHEMICAL MODIFICATION OF TREHALOSE .17. SYNTHESIS OF ALLO-ANALOG OF TREHALOSE [J].

BIRCH, GG ;

LEE, CK ;

RICHARDSON, AC ;

ALI, Y .

CARBOHYDRATE RESEARCH, 1976, 49 (JUL) :153-161

[5]

BIRCH GG, 1974, J FOOD SCI, V39, P947, DOI 10.1111/j.1365-2621.1974.tb07283.x

[6] CRYSTAL-STRUCTURE OF ALPHA,ALPHA-TREHALOSE DIHYDRATE FROM 3 INDEPENDENT X-RAY DETERMINATIONS [J].

BROWN, GM ;

ROHRER, DC ;

BERKING, B ;

BEEVERS, CA ;

GOULD, RO ;

SIMPSON, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1972, B 28 (NOV15) :3145-3158

[7] CALCIUM-ION BINDING TO UNCHARGED SUGARS - CRYSTAL-STRUCTURES OF CALCIUM BROMIDE COMPLEXES OF LACTOSE, GALACTOSE, AND INOSITOL [J].

BUGG, CE ;

COOK, WJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1972, (12) :727-&

[8] CALCIUM INTERACTIONS WITH D-GLUCANS - CRYSTAL-STRUCTURE OF ALPHA,ALPHA-TREHALOSE-CALCIUM BROMIDE MONOHYDRATE [J].

COOK, WJ ;

BUGG, CE .

CARBOHYDRATE RESEARCH, 1973, 31 (02) :265-275

[9] GENERAL DEFINITION OF RING PUCKERING COORDINATES [J].

CREMER, D ;

POPLE, JA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (06) :1354-1358

[10] THE CRYSTAL-STRUCTURE OF ANHYDROUS ALPHA,ALPHA-TREHALOSE AT -150-DEGREES [J].

JEFFREY, GA ;

NANNI, R .

CARBOHYDRATE RESEARCH, 1985, 137 (MAR) :21-30

← 1 2 3 →