SYNTHESIS AND CRYSTAL-STRUCTURE OF THE HOMOLEPTIC URANIUM(IV) THIOLATES [(THF)3NA(MU-SR)3U(MU-SR)3NA(THF)3] (THF = TETRAHYDROFURAN - R = BUT OR PH)

被引：30

作者：

LEVERD, PC ^{[1
]}

LANCE, M ^{[1
]}

NIERLICH, M ^{[1
]}

VIGNER, J ^{[1
]}

EPHRITIKHINE, M ^{[1
]}

机构：

[1] CEA CE SACLAY,DRECAM,SERV CHIM MOLEC,CRISTALLOG LAB,CNRS,URA 331,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1993年 / 14期

关键词：

D O I：

10.1039/dt9930002251

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The uranium(IV) hexathiolate complexes [(thf)3Na(mu-SR)3U(mu-SR)3Na(thf)3] (thf = tetrahydrofuran; R = Bu(n), Pr(i), Bu(t) or Ph) were prepared by treatment of UCl4 or U(BH4)4 with the corresponding NaSR reagent. The crystal structures of the tert-butyl and phenyl derivatives have been determined. Reaction of U(SBu(n))4 with NaSBu(n) gave the anion [U(SBu(n))6]2 which, by protonation with NEt3HBPh4, was transformed back into U(SBu(n))4.

引用

页码：2251 / 2254

页数：4

共 33 条

[11] STRUCTURE OF A CUBIC FORM OF TETRAETHYLAMMONIUM OCTAKIS(THIOCYANATO-N)THORATE(IV),[N(C2H5)4]4[TH(NCS)8] [J].

CHARPIN, P ;

LANCE, M ;

NAVAZA, A .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 1983, 39 (FEB) :190-192

[12]

CLAPPE C, COMMUNICATION

[13] ISOLATION OF THE ANIONS [M(CO)5(SH)]- AND [M2(CO)10(MU-SH)]-(M=CR, MO, AND W) AS SALTS OF THE SODIUM (18-CROWN-6-ETHER) CATION - X-RAY-ANALYSIS OF THE SODIUM CARBONYL LINKED POLYMERIC STRUCTURES OF THE TUNGSTEN SPECIES [J].

COOPER, MK ;

DUCKWORTH, PA ;

HENRICK, K ;

MCPARTLIN, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1981, (12) :2357-2364

[14] CHEMISTRY, SPECTROSCOPY, AND ISOTOPE-SELECTIVE INFRARED PHOTOCHEMISTRY OF A VOLATILE URANIUM COMPOUND TAILORED FOR 10-MU-M ABSORPTION - U(OCH3)6 [J].

CUELLAR, EA ;

MILLER, SS ;

MARKS, TJ ;

WEITZ, E .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (14) :4580-4589

[15] SYNTHESIS AND CHARACTERIZATION OF THE URANIUM ALKYLTHIOLATE COMPLEX U(SPR-I)2(HBPZ3)2 [J].

DOMINGOS, A ;

DEMATOS, AP ;

SANTOS, I .

POLYHEDRON, 1992, 11 (13) :1601-1606

[16] BIS[HYDROTRIS(PYRAZOLYL)BORATE] THORIUM(IV) COMPLEXES - SYNTHESIS AND CHARACTERIZATION OF ALKYL, THIOLATE, ALKOXIDE AND ARYLOXIDE DERIVATIVES AND THE X-RAY CRYSTAL-STRUCTURE OF TH(HBPZ3)2(OPH)2 [J].

DOMINGOS, A ;

MARCALO, J ;

DEMATOS, AP .

POLYHEDRON, 1992, 11 (08) :909-915

[17] URANIUM(IV) CHLORIDE [J].

HERMANN, JA ;

SUTTLE, JF .

INORGANIC SYNTHESES, 1957, 5 :143-145

[18]

JOHNSON CK, 1976, ORTEP ORNL5138 REP

[19] ORGANIC COMPOUNDS OF URANIUM .2. URANIUM(IV) AMIDES, ALKOXIDES AND MERCAPTIDES [J].

JONES, RG ;

KARMAS, G ;

MARTIN, GA ;

GILMAN, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1956, 78 (17) :4285-4286

[20] SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND PROPERTIES OF THE ORGANOTHORIUM ALKYLTHIOLATE COMPLEX [(CH3)5C5]2TH(SCH2CH2CH3)2 [J].

LIN, ZR ;

BROCK, CP ;

MARKS, TJ .

INORGANICA CHIMICA ACTA, 1988, 141 (01) :145-149

← 1 2 3 4 →