Boron clusters in liquid crystals

被引：56

作者：

Kaszynski, P

Huang, JP

Jenkins, GS

Bairamov, KA

Lipiak, D

机构：

[1] Vanderbilt Univ, Nashville, TN

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1995年 / 260卷

关键词：

D O I：

10.1080/10587259508038705

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

3-Dimensional aromatic moiety was used for the first time in the synthesis of liquid crystals. Several of the prepared compounds, based on sigma-aromatic boron clusters 1 and 2, show only nematic mesophases with relatively high T-i, good electrochemical but limited thermal stability. Absorption and emission spectra of pyridine derivative 15 are reported. Semiempirical methods were employed in evaluation of molecular properties and design of molecules with large coaxial dipole moments.

引用

收藏

页码：315 / 332

页数：18

相关论文

共 33 条

[11] SOME CONDENSATION REACTIONS OF ISOPROPYLIDENE MALONATE [J].

HEDGE, JA ;

KRUSE, CW ;

SNYDER, HR .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (09) :3166-&

[12] CHEMISTRY OF BORANES .22. POLYHEDRAL REARRANGEMENT OF DERIVATIVES OF B10H102- + B12H122- [J].

HERTLER, WR ;

MUETTERTIES, EL ;

KNOTH, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (24) :5434-&

[13] NEW WEAKLY COORDINATING ANIONS .2. DERIVATIZATION OF THE CARBORANE ANION CB11H12- [J].

JELINEK, T ;

BALDWIN, P ;

SCHEIDT, WR ;

REED, CA .

INORGANIC CHEMISTRY, 1993, 32 (10) :1982-1990

[14] CHEMISTRY OF COMPOUNDS WITH THE 1-CARBA-CLOSO-DODECABORANE(12) FRAMEWORK [J].

JELINEK, T ;

PLESEK, J ;

HERMANEK, S ;

STIBR, B .

COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1986, 51 (04) :819-829

[15]

KASZYNSKI P, 1994, 23 SETCA C MAY 20 21

[16] CHEMISTRY OF BORANES .23. B10H9S(CH3)2- AND B10H8[S(CH3)2]2 [J].

KNOTH, WH ;

HERTLER, WR ;

MUETTERT.EL .

INORGANIC CHEMISTRY, 1965, 4 (03) :280-&

[17] CHEMISTRY OF BORANES .26. INNER DIAZONIUM SALTS 1,10-B10H8 (N2) 2, -B10CL8(N2)2, AND -B10I8(N2)2 [J].

KNOTH, WH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (05) :935-&

[18] REGIOSELECTIVE SYNTHESIS OF [1-B10H9(SH)]2- AND [2-B10H9(SH)]2- - POTENTIAL AGENTS FOR BORON NEUTRON-CAPTURE THERAPY OF BRAIN-TUMORS [J].

KOMURA, M ;

NAKAI, H ;

SHIRO, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1987, (08) :1953-1956

[19]

KORSHAK VV, 1982, IAN SSSR KH, V31, P1904

[20]

Muetterties E. L., 1975, BORON HYDRIDE CHEM

← 1 2 3 4 →