DETERMINATION OF THE VIBRATIONAL-ENERGY RELAXATION-TIME OF THE AZIDE ION IN PROTIC SOLVENTS BY 2-COLOR TRANSIENT INFRARED-SPECTROSCOPY

被引：88

作者：

OWRUTSKY, JC ^{[1
]}

KIM, YR ^{[1
]}

LI, M ^{[1
]}

SARISKY, MJ ^{[1
]}

HOCHSTRASSER, RM ^{[1
]}

机构：

[1] UNIV PENN,RES STRUCT MATTER LAB,PHILADELPHIA,PA 19104

来源：

CHEMICAL PHYSICS LETTERS | 1991年 / 184卷 / 5-6期

基金：

美国国家科学基金会; 美国国家卫生研究院;

关键词：

D O I：

10.1016/0009-2614(91)80002-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The vibrational energy relaxation times (T1) of the antisymmetric stretch (nu-3) of the azide ion (N3-) in various protic solvents have been measured to be 3 ps using transient two-color infrared spectroscopy.

引用

页码：368 / 374

页数：7

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