A TE2N6LI4 CAGE CONTAINING THE TRIS(TERT-BUTYLIMIDO)TELLURITE DIANION

被引：58

作者：

CHIVERS, T

GAO, XL

PARVEZ, M

机构：

[1] Department of Chemistry, University of Calgary, Calgary, Alberta

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

HETEROCYCLES; LITHIUM COMPOUNDS; NITROGEN COMPOUNDS; TELLURIUM COMPOUNDS;

D O I：

10.1002/anie.199525491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A nonexplosive, easy‐to‐handle TeN reagent is the Li2 derivative of the tris(tert‐butylimido)tellurite dianion 1, which can be prepared from [(tBuN)Te]2(μ‐NtBu)2 and tBuNHLi. The Te2N6Li4 cage in 1 adopts a distorted hexagonal prismatic structure. The reaction of 1 with PhPCl2 or PhBCl2 produces the spirocycle 2 and the four‐membered ring 3, respectively. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2549 / 2551

页数：3

共 30 条

[21] ALKALI-METAL DERIVATIVES OF SULFINIMIDAMIDES - PREPARATION AND CRYSTAL-STRUCTURES [J].