[((ET2O)2CLGA)GA(GACL2(ET2O))3] - A MOLECULAR-COMPOUND WITH A TETRAHEDRAL GA5 UNIT

被引：39

作者：

LOOS, D

SCHNOCKEL, H

FENSKE, D

机构：

[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,D-80333 MUNICH,GERMANY

[2] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76128 KARLSRUHE,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxidation states between 0 and II can be formally assigned to the five Ga atoms in the title compound 1 depending on the coordinating ligands. Each Ga atom has a tetrahedral coordination environment; the central atom is surrounded by the other four Ga atoms. Compound 1 crystallizes at -30-degrees-C from a cryochemically prepared solution of GaCl in toluene/diethyl ether.

引用

页码：1059 / 1060

页数：2

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