[((ET2O)2CLGA)GA(GACL2(ET2O))3] - A MOLECULAR-COMPOUND WITH A TETRAHEDRAL GA5 UNIT

被引:39
作者
LOOS, D
SCHNOCKEL, H
FENSKE, D
机构
[1] UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1,D-80333 MUNICH,GERMANY
[2] UNIV KARLSRUHE,INST ANORGAN CHEM,D-76128 KARLSRUHE,GERMANY
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期
关键词
D O I
10.1002/anie.199310591
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Oxidation states between 0 and II can be formally assigned to the five Ga atoms in the title compound 1 depending on the coordinating ligands. Each Ga atom has a tetrahedral coordination environment; the central atom is surrounded by the other four Ga atoms. Compound 1 crystallizes at -30-degrees-C from a cryochemically prepared solution of GaCl in toluene/diethyl ether.
引用
收藏
页码:1059 / 1060
页数:2
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