THE CRYSTAL AND MOLECULAR-STRUCTURE OF TRIBENZYLSILANOL BY RIETVELD REFINEMENT OF POWDER X-RAY-DIFFRACTION DATA

被引：8

作者：

LIGHTFOOT, P ^{[1
]}

GLIDEWELL, C ^{[1
]}

BRUCE, PG ^{[1
]}

机构：

[1] UNIV ST ANDREWS,SCH CHEM,ST ANDREWS KY16 9ST,FIFE,SCOTLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 466卷 / 1-2期

关键词：

TRIBENZYLSILANOL; HYDROGEN BONDING; X-RAY POWDER DIFFRACTION; RIETVELD REFINEMENT; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)88028-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structure of tibenzylsilanol ((PhCH(2))(3)SiOH) has been refined by the Rietveld method from X-ray powder diffraction data collected with a conventional laboratory powder diffractometer. The compound is isostructural with tribenzylmethanol ((PhCH(2))(3)COH). The crystal consists of isolated molecules with approximate threefold molecular symmetry: there is no hydrogen bonding between the molecules.

引用

页码：51 / 54

页数：4

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