SOLUTION BEHAVIOR OF STYRENE ETHYLENE OXIDE BLOCK COPOLYMERS

被引:31
作者
NAKAMURA, K [1 ]
ENDO, R [1 ]
TAKEDA, M [1 ]
机构
[1] SCI UNIV TOKYO,FAC SCI,DEPT CHEM,SHINJUKU,TOKYO,JAPAN
关键词
MAGNETIC RESONANCE - POLYMERIZATION - Copolymerization - SOLUTIONS - Viscosity - STYRENE - Polymerization;
D O I
10.1002/pol.1976.180140111
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In the reported experimental study, hydrophobic - hydrophilic water-soluble block copolymers were prepared by ″living″ anionic polymerization. They consist of a PS block and a polyethylene oxide block. From data on solution viscosity and high-resolution MNR in water, the molecular dimensions of the two-blocks copolymers are found similar to that of polyethylene glycols of the same mol. wt in the same solvent. These block copolymers exhibit microphase separation.
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页码:135 / 142
页数:8
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