DIPPED ADCLUSTER MODEL AND SAC-CI METHOD APPLIED TO HARPOONING, CHEMILUMINESCENCE AND ELECTRON-EMISSION IN HALOGEN CHEMISORPTION ON ALKALI-METAL SURFACE

被引：12

作者：

NAKATSUJI, H ^{[1
]}

KUWANO, R ^{[1
]}

MORITA, H ^{[1
]}

NAKAI, H ^{[1
]}

机构：

[1] INST FUNDAMENTAL CHEM, SAKYO KU, KYOTO 606, JAPAN

来源：

JOURNAL OF MOLECULAR CATALYSIS | 1993年 / 82卷 / 2-3期

关键词：

ALKALI-METAL SURFACE; CHEMILUMINESCENCE; ELECTRON EMISSION; HALOGEN CHEMISORPTION; HARPOONING;

D O I：

10.1016/0304-5102(93)80033-Q

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The methodology of our laboratory, the dipped adcluster model (DAM) and the symmetry adapted cluster configuration interaction (SAC-CI) method, are briefly reviewed and successfully applied to the electron transfer processes, harpooning, surface chemiluminescence, and surface electron emission, in the course of the chemisorption of halogen molecule on an alkali metal surface. This success encourages us to apply our methodology to surface photochemistry.

引用

页码：211 / 228

页数：18

共 33 条

[11] THE A ELECTRONIC STATE OF ACETYLENE - GEOMETRY AND AXIS-SWITCHING EFFECTS [J].