SYNTHESIS OF ANTITUMOR CYCLIC PEROXY KETALS RELATED TO CHONDRILLIN AND XESTIN-A AND XESTIN-B

被引：27

作者：

SNIDER, BB

SHI, ZP

机构：

[1] Department of Chemistry, Brandeis University, Waltham

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1990年 / 55卷 / 22期

关键词：

D O I：

10.1021/jo00309a003

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

: A seven-step synthesis of the antitumor cyclic peroxy ketals 2b and 18 from phenol has been carried out in 15% overall yield. The key step is the photooxygenation of acetoxy diene 10 using rose bengal as a sensitizer and a sun lamp to give peroxy hemiketals 16 and 17. © 1990, American Chemical Society. All rights reserved.

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页码：5669 / 5671

页数：3

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