ALDOL REACTIONS PROMOTED BY DIETHYLZINC - THE X-RAY CRYSTAL-STRUCTURE AND STEREOCHEMISTRY OF DYPNOPINACOL

被引：6

作者：

CHALONER, PA

HITCHCOCK, PB

LANGADIANOU, E

READEY, MJ

机构：

[1] School of Chemistry and Molecular Sciences, University of Sussex, Falmer, Brighton

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 42期

关键词：

ALDOL; DIETHYLZINC; CONJUGATE REDUCTION; DYPNOPINACOL;

D O I：

10.1016/S0040-4039(00)79458-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Diethylzinc reacted with acetophenone to give the aldol dimer, 1,3-diphenyl-2-butene-1-one together with small amounts of dypnopinacol 1-(2-hydroxy-6-methyl-2,4,6-triphenylcyclohex-3-enyl)-1-phenylmethanone. The structure of dypnopinacol was established in an X-ray diffraction study.

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页码：6037 / 6038

页数：2

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