SYNTHESIS AND STRUCTURE OF AN IONIC BERYLLIUM-CARBENE COMPLEX

被引：144

作者：

HERRMANN, WA

RUNTE, O

ARTUS, G

机构：

[1] Anorganisch-chemisches Institut der Technischen Uniuersität München, D-85747 Garching

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 501卷 / 1-2期

关键词：

BERYLLIUM; HETEROCYCLIC CARBENE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(95)05615-V

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Lewis-acidic metal ion Be2+ forms stable adducts with the carbene 1,3-dimethylimidazolin-2-ylidene (L). The pronounced nucleophilicity of the ligand is encountered in the cleavage of the polymeric structure of BeCl2 with consecutive heterolysis to yield the ionic coordination compound [L(3)BeCl]Cl-+(-).

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页码：C1 / C4

页数：4

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