A RIGOROUS KINETIC APPROACH TO MODEL PRIMARY OXIDATIVE STEPS OF PHOTOCATALYTIC DEGRADATIONS

被引：41

作者：

MINERO, C

机构：

[1] Dept. of Analytical Chemistry, University of Torino, Torino

来源：

SOLAR ENERGY MATERIALS AND SOLAR CELLS | 1995年 / 38卷 / 1-4期

关键词：

D O I：

10.1016/0927-0248(94)00234-7

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

A kinetic model for the early stages of oxidation of an organic compound over irradiated semiconductors is presented. The model considers only the simpler cases, having the advantage of simplicity and of analytical solutions to the general differential equation. The obtained relationships are able to justify (i) the observed decays of C-i(t) versus time, (ii) the observed dependencies of the measured kinetic constants on initial substrate concentration, (iii) on the catalyst concentration, and (iv) on the light intensity.

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页码：421 / 430

页数：10

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