TRIPLET-STATE IR SPECTROSCOPY OF AROMATIC HOMOCYCLES AND HETEROCYCLES

被引：8

作者：

KRUMSCHMIDT, H ^{[1
]}

KRYSCHI, C ^{[1
]}

机构：

[1] HEINRICH HEINE UNIV,LEHRSTUHL FESTKORPERSPEKTROSKOPIE,W-4000 DUSSELDORF,GERMANY

来源：

CHEMICAL PHYSICS | 1991年 / 154卷 / 03期

关键词：

D O I：

10.1016/0301-0104(91)85028-F

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The triplet (T1) state IR spectra of 9 aromatic compounds, i.e. acenaphthene, biphenyl, chrysene, coronene, fluorene, 2-phenyl-pyridine, 5-monoazaphenanthrene (5-MAP) and triphenylene, embedded in rigid glass at 77 K are reported. The symmetry of the T1 vibrations has been determined from IR linear dichroism measurements of T1 excited molecules in stretched polymer films. The T1 vibrational spectra were tentatively assigned on the basis of analogous experimental and theoretical results for the respective ground-state molecules.

引用

页码：459 / 468

页数：10

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