SURFACE DEFLUORINATION OF PTFE BY SODIUM ATOMS

被引：55

作者：

TASKER, S ^{[1
]}

CHAMBERS, RD ^{[1
]}

BADYAL, JPS ^{[1
]}

机构：

[1] UNIV DURHAM,DEPT CHEM,SCI LABS,DURHAM DH1 3LE,ENGLAND

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1994年 / 98卷 / 47期

关键词：

D O I：

10.1021/j100098a046

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reaction of sodium atoms with poly(tetrafluoroethylene) (PTFE) under ultrahigh vacuum conditions has been followed by X-ray photoelectron spectroscopy (XPS). Surface defluorination and formation of NaF are found to occur. Initial stages of reaction result in desorption of NaF molecules; this is followed by permeation of Na adatoms into the polymer subsurface region to yield trapped NaF moieties.

引用

页码：12442 / 12446

页数：5

共 50 条

[1] ALKALI-METAL-ATOM CHEMISORPTION ONTO A METAL-SURFACE
ANDRIOTIS, AN
[J]. PHYSICAL REVIEW B, 1990, 42 (14): : 9217 - 9220
[2] ATOMIC-STRUCTURE OF ALKALI-METAL OVERLAYERS ON THE SI(001) SURFACE
BATRA, IP
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1990, 8 (04): : 3425 - 3431
[3] BAYLIFF AE, 1988, J CHEM SOC P1, V2, P201
[4] BRIGGS D, 1983, PRACTICAL SURFACE AN
[5] CHEMICAL INTERACTION OF METALS WITH POLYTETRAFLUOROETHYLENE
CADMAN, P
GOSSEDGE, GM
[J]. JOURNAL OF MATERIALS SCIENCE, 1979, 14 (11) : 2672 - 2678
[6] STUDIES OF POLYTETRAFLUOROETHYLENE TRANSFER LAYERS PRODUCED BY RUBBING IN ULTRAHIGH-VACUUM USING A RELATIVELY SIMPLE APPARATUS
CADMAN, P
GOSSEDGE, GM
[J]. WEAR, 1978, 51 (01) : 57 - 65
[7] CHAKRABARTI N, 1988, MACROMOLECULES, V21, P5487
[8] ALKALI-METAL ATOMS ADSORBED ON NI(111) - SURFACE INTERACTIONS
CHANDAVARKAR, S
DIEHL, RD
FAKE, A
JUPILLE, J
[J]. SURFACE SCIENCE, 1989, 211 (1-3) : 432 - 440
[9] ADHESION STUDIES OF METALS ON FLUOROCARBON POLYMER-FILMS
CHANG, CA
KIM, YK
SCHROTT, AG
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1990, 8 (04): : 3304 - 3309
[10] ENHANCED CU-TEFLON ADHESION BY PRESPUTTERING PRIOR TO THE CU DEPOSITION
CHANG, CA
BAGLIN, JEE
SCHROTT, AG
LIN, KC
[J]. APPLIED PHYSICS LETTERS, 1987, 51 (02) : 103 - 105

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