N-ACYL-N-ALKYLCARBAMOYLOXY RADICALS - ENTRIES TO AMIDYL RADICALS BY DECARBOXYLATION AND TO ALPHA-AMIDE RADICALS BY RADICAL TRANSLOCATION

被引：34

作者：

ESKER, JL ^{[1
]}

NEWCOMB, M ^{[1
]}

机构：

[1] WAYNE STATE UNIV,DEPT CHEM,5101 CASS AVE,DETROIT,MI 48202

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 40期

关键词：

D O I：

10.1016/S0040-4039(00)61087-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

N'-Acyl-N-hydroxypyridine-2-thione carbamates react in radical chain reactions to give the title radicals which can decarboxylate or react by intramolecular hydrogen atom transfer; the competing reaction pathways are controlled by the structure of the alkyl group and the conformation of the precursor which can be influenced by addition of a Lewis acid.

引用

页码：5913 / 5916

页数：4

共 14 条

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