DIELECTRIC-PROPERTIES OF GOLD-CONTAINING PLASMA-POLYMERIZED THIN-FILMS

被引:24
作者
CANET, P
LAURENT, C
AKINNIFESI, J
DESPAX, B
机构
[1] Laboratoire de Génie Electrique, CNRS URA 304, Université Paul Sabatier, 31062 Toulouse
关键词
D O I
10.1063/1.351587
中图分类号
O59 [应用物理学];
学科分类号
摘要
Electrical properties of gold-containing plasma-polymerized thin films have been studied in the dielectric regime (isolated conducting clusters dispersed in a polymeric matrix). dc measurements over a wide temperature range provide evidence for a transport process involving the matrix itself as opposed to tunneling directly across the insulating barrier between metallic clusters. The films display space-charge-limited conduction which is due to the existence of trap states in the polymeric phase. An exponential distribution of traps with a peak value of the order of 10(17) cm-3 eV-1 has been deduced from the voltage-current data. The ac behavior is dominated by conduction losses at low frequency with a dissipation peak due to interfacial polarization between metal and matrix in the kHz range. Another relaxation is found for gold-rich films. The full interpretation requires more details on the polymeric phase which composition and electrical properties change gradually with an increasing gold concentration.
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页码:2423 / 2431
页数:9
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