CARBENE FORMATION, HYDROGEN MIGRATION, AND FLUORESCENCE IN THE EXCITED-STATES OF DIALKYLDIAZIRINES

被引：151

作者：

MODARELLI, DA ^{[1
]}

MORGAN, S ^{[1
]}

PLATZ, MS ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT CHEM,120 W 18TH AVE,COLUMBUS,OH 43210

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 18期

关键词：

D O I：

10.1021/ja00044a013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of 3,3-dimethyldiazirine produces an electronically excited singlet state which decays by at least three competitive pathways: (1) fluorescence, (2) nitrogen extrusion and carbene formation, and (3) alpha-hydrogen migration and propylene formation concurrent with nitrogen extrusion. The temperature dependence of the fluorescence intensity was determined.

引用

页码：7034 / 7041

页数：8

共 81 条

[1]

ADDING AC, 1966, J CHEM SOC CHEM COMM, P657

[2]

BAER TA, 1971, J AM CHEM SOC, V93, P954

[3] 1-NAPHTHYLCARBENE - SPECTROSCOPY, KINETICS, AND MECHANISMS [J].

BARCUS, RL ;

HADEL, LM ;

JOHNSTON, LJ ;

PLATZ, MS ;

SAVINO, TG ;

SCAIANO, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (14) :3928-3937

[4]

BARON WJ, 1973, CARBENES, V1, P2

[5] PHOTOGENERATED REAGENTS FOR MEMBRANES - SELECTIVE LABELING OF INTRINSIC MEMBRANE-PROTEINS IN THE HUMAN-ERYTHROCYTE MEMBRANE [J].

BAYLEY, H ;

KNOWLES, JR .

BIOCHEMISTRY, 1980, 19 (17) :3883-3892

[6] PHOTOGENERATED REAGENTS FOR MEMBRANE LABELING .2. PHENYLCARBENE AND ADAMANTYLIDENE FORMED WITHIN LIPID BILAYER [J].

BAYLEY, H ;

KNOWLES, JR .

BIOCHEMISTRY, 1978, 17 (12) :2420-2423

[7] RATES FOR 1,2 MIGRATION IN ALKYLCHLOROCARBENES [J].

BONNEAU, R ;

LIU, MTH ;

RAYEZ, MT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) :5973-5974

[8]

BONNEAU R, 1990, J AM CHEM SOC, V111, P5642

[9] ROLES OF MULTIPLICITY AND ELECTRONIC EXCITATION ON INTRA-MOLECULAR REACTIONS OF ALKYLCARBENES IN CONDENSED PHASE [J].

CHANG, KT ;

SHECHTER, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (17) :5082-5084

[10]

CHAPMAN OL, 1988, J AM CHEM SOC, V110, P50

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