CARBENE FORMATION, HYDROGEN MIGRATION, AND FLUORESCENCE IN THE EXCITED-STATES OF DIALKYLDIAZIRINES

被引：151

作者：

MODARELLI, DA ^{[1
]}

MORGAN, S ^{[1
]}

PLATZ, MS ^{[1
]}

机构：

[1] OHIO STATE UNIV,DEPT CHEM,120 W 18TH AVE,COLUMBUS,OH 43210

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 18期

关键词：

D O I：

10.1021/ja00044a013

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of 3,3-dimethyldiazirine produces an electronically excited singlet state which decays by at least three competitive pathways: (1) fluorescence, (2) nitrogen extrusion and carbene formation, and (3) alpha-hydrogen migration and propylene formation concurrent with nitrogen extrusion. The temperature dependence of the fluorescence intensity was determined.

引用

页码：7034 / 7041

页数：8

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