A NEW FORM OF COORDINATED CARBON - A C3 CHAIN THAT IS ANCHORED BY A TRANSITION-METAL ON EACH END AND SPANNED BY A 1/3

被引：37

作者：

WENG, WQ ^{[1
]}

ARIF, AM ^{[1
]}

GLADYSZ, JA ^{[1
]}

机构：

[1] UNIV UTAH,DEPT CHEM,SALT LAKE CITY,UT 84112

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 06期

关键词：

D O I：

10.1002/anie.199308911

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A trirhenium carbene complex, containing [C3OMe core, PrePared from [Re]C=CLi, [Re2(CO)10], and Me3OBF4, leads to-complex 1 after abstraction of the methoxy group with BF3 and skeletal rearrangement. According to X-ray crystal structure analysis, 1 exists predominantly as the resonance structure shown on the right. [Re] = (eta5-C5Me5)Re(NO)(PPh3).

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页码：891 / 892

页数：2

相关论文

共 36 条

[1]

ADAMS CJ, 1992, J CHEM SOC CHEM COMM, P1315

[2] PREPARATION, CHARACTERIZATION, AND SEQUENTIAL TRANSFORMATION OF DICARBIDE CLUSTER COMPOUNDS WITH PERMETALLATED ETHYNE, ETHENE, AND ETHANE STRUCTURES [J].

AKITA, M ;

SUGIMOTO, S ;

TANAKA, M ;

MOROOKA, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (19) :7581-7582

[3] HYDROCARBON-BRIDGED COMPLEXES .16. SYNTHESIS AND STRUCTURE OF THE NOVEL MU-2-CARBIDO COMPLEX [(TPP)FE=C=RE(CO)4RE(CO)5] [J].

BECK, W ;

KNAUER, W ;

ROBL, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (03) :318-320

[4]

Beck W., 1990, ANGEW CHEM, V102, P331

[5] A RU(II) ENYNYL COMPLEX MEDIATES THE CATALYTIC DIMERIZATION OF 1-ALKYNES TO Z-1,4-DISUBSTITUTED ENYNES [J].

BIANCHINI, C ;

PERUZZINI, M ;

ZANOBINI, F ;

FREDIANI, P ;

ALBINATI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (14) :5453-5454

[6] SYNTHESIS AND STRUCTURE OF A NEW BIS[(TRIMETHYLPHOSPHANE)TITANOCENE] COMPLEX WITH A BRIDGING C-2 UNIT [J].

BINGER, P ;

MULLER, P ;

PHILIPPS, P ;

GABOR, B ;

MYNOTT, R ;

HERRMANN, AT ;

LANGHAUSER, F ;

KRUGER, C .

CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (10) :2209-2212

[7]

BODGAN PL, 1987, ORGANOMETALLICS, V6, P1377

[8]

BRADLEY JS, 1983, ADV ORGANOMET CHEM, V22, P1

[9] HYDRIDE DONATION REACTIONS OF TRANSITION-METAL FORMYL COMPLEXES [J].

CASEY, CP ;

NEUMANN, SM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1978, 100 (08) :2544-2545

[10] REARRANGEMENT OF A PROPARGYL VINYL RHENIUM COMPLEX TO A RHENIUM ALLENYL VINYL KETONE COMPLEX [J].

CASEY, CP ;

UNDERINER, TL ;

VOSEJPKA, PC ;

GAVNEY, JA ;

KIPROF, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (27) :10826-10834

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