ENERGY-CONVERSION AT LIQUID/LIQUID INTERFACES - ARTIFICIAL PHOTOSYNTHETIC SYSTEMS

被引：39

作者：

VOLKOV, AG

GUGESHASHVILI, MI

DEAMER, DW

机构：

[1] Department of Chemistry, University of California, Santa Cruz

来源：

ELECTROCHIMICA ACTA | 1995年 / 40卷 / 18期

关键词：

MULTIELECTRON REACTION; ARTIFICIAL PHOTOSYNTHESIS; LIQUID LIQUID INTERFACE; AMPHIPHILIC MOLECULES; MONOLAYERS; PHOTOELECTROCHEMISTRY; ITIES;

D O I：

10.1016/0013-4686(95)00214-Y

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

This chapter focuses on multielectron reactions in organized assemblies of molecules at the liquid/liquid interface. We describe the thermodynamic and kinetic parameters of such reactions, including the structure of the reaction centers, charge movement along the electron transfer pathways, and the role of electric double layers in artificial photosynthesis. Some examples of artificial photosynthesis at the oil/water interface are considered, including water photooxidation to the molecular oxygen, oxygen photoreduction, photosynthesis of amphiphilic compounds and proton evolution by photochemical processes.

引用

收藏

页码：2849 / 2868

页数：20

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