RHODIUM-CATALYZED HYDROAMINATION-HYDROARYLATION OF NORBORNENE WITH ANILINE, TOLUIDINES OR DIPHENYLAMINE

被引：89

作者：

BRUNET, JJ ^{[1
]}

COMMENGES, G ^{[1
]}

NEIBECKER, D ^{[1
]}

PHILIPPOT, K ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE,F-31077 TOULOUSE,FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 469卷 / 02期

关键词：

RHODIUM; NORBORNENE; HYDROARYLATION; HYDROAMINATION; CATALYSIS;

D O I：

10.1016/0022-328X(94)88076-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The condensation of aniline, toluidines or diphenylamine with norbornene tetrahydrofuran is promoted by a system generated from Li(n)Bu, ArNH2 and [{(PEt3)2RhCl}2]. Aniline and m- and p-toluidines lead to a mixture of hydroamination and hydroarylation products whereas o-toluidine and diphenylamine lead to the hydroarylation product only. When conducted in the amine as solvent, the reaction is catalytic with respect to both lithium and rhodium.

引用

页码：221 / 228

页数：8

共 30 条

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