SYNTHESIS OF UNSYMMETRICAL TETRAKIS(ALKYLSULFANYL)TETRATHIAFULVALENE DERIVATIVES

被引：25

作者：

GEMMELL, C

JANAIRO, GC

KILBURN, JD

UECK, H

UNDERHILL, AE

机构：

[1] UNIV SOUTHAMPTON,DEPT CHEM,SOUTHAMPTON SO17 1BJ,HANTS,ENGLAND

[2] UNIV COLL N WALES,DEPT CHEM,BANGOR LL57 2UW,GWYNEDD,WALES

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1994年 / 19期

关键词：

D O I：

10.1039/p19940002715

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The p-acetoxybenzylsulfanyl protecting group is compatible with the triethylphosphite mediated cross-coupling of 4,5-bis(alkylsulfanyl)-1,3-dithiol-2-ones, providing access to bis(protected)-tetrathiafulvalenes, and thus to tetrathiafulvalenedithiolate dianion 10, which can be alkylated to give unsymmetrical tetrakis (alkylsulfanyl)tetrathiafulvalene derivatives.

引用

页码：2715 / 2720

页数：6

共 24 条

[21] USE OF ORTHO-HYDROXYBENZYL AND PARA-HYDROXYBENZYL FUNCTIONS AS BLOCKING GROUPS WHICH ARE REMOVABLE WITH BASE [J].