INTERMOLECULAR REACTION OF NITROXIDE RADICALS WITH BIRADICAL INTERMEDIATES GENERATED FROM AROMATIC ENEDIYNES

被引:31
作者
GRISSOM, JW
GUNAWARDENA, GU
机构
关键词
D O I
10.1016/0040-4039(95)00967-h
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
1, 4-Dehydronaphthalene biradicals generated by thermolysis of aromatic enediynes can be trapped with the nitroxide radical TEMPO. The isolated products, however, are not the direct trapping products but 1, 4-naphthoquinones resulting from the homolysis of N-O bonds of trapping products.
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页码:4951 / 4954
页数:4
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