OXYGEN-PRESSURE, THE KEY FACTOR FOR OPTIMIZATION OF SUPERCONDUCTIVITY IN THE 1212-PHASE PB1-XSR2CA0.5Y0.5CU2+XO7+/-DELTA

被引:32
作者
MAIGNAN, A [1 ]
ROUILLON, T [1 ]
GROULT, D [1 ]
PROVOST, J [1 ]
HERVIEU, M [1 ]
MICHEL, C [1 ]
RAVEAU, B [1 ]
LIU, RS [1 ]
EDWARDS, PP [1 ]
机构
[1] UNIV CAMBRIDGE,IRC SUPERCONDUCT,CAMBRIDGE CB3 0HE,ENGLAND
来源
PHYSICA C | 1991年 / 177卷 / 4-6期
关键词
D O I
10.1016/0921-4534(91)90503-Q
中图分类号
O59 [应用物理学];
学科分类号
摘要
The influence of oxygen pressure upon superconducting properties of lead-based 1212 copper oxides Pb1-xSr2Ca0.5Y0.5Cu2+xO7 +/- delta has been investigated as a function of time and annealing temperature. Annealings of (Pb0.7Cu0.3)Sr2Ca0.5Y0.5Cu2O7 +/- delta at 400-degrees-C for 10 h show that this material becomes superconductive as the oxygen pressure reaches 10 bar, the critical temperature being increased from 0 to 29 K. The maximum value of T(c) = 42 K is obtained for an oxygen pressure ranging between 40 and 60 bar. Annealing at 20 bar for 65 h show that T(c) increases up to an annealing temperature of 500-degrees-C and decreases abruptly beyond this temperature.
引用
收藏
页码:461 / 468
页数:8
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