COORDINATION OF DIOXYGEN IN 3 REPRESENTATIVE TRANSITION-METAL CATIONS - FEO2+ CRO2+ AND [CH3RE(O-2)(2)O](+)

被引：30

作者：

SCHRODER, D

FIEDLER, A

HERRMANN, WA

SCHWARZ, H

机构：

[1] TECH UNIV BERLIN,INST ORGAN CHEM,D-10623 BERLIN,GERMANY

[2] TECH UNIV MUNICH,INST ANORGAN CHEM,W-8000 MUNICH,GERMANY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 22期

关键词：

AB INITIO CALCULATIONS; OXYGEN ACTIVATION; MASS SPECTROMETRY; TRANSITION METAL OXIDES;

D O I：

10.1002/anie.199525171

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

How is dioxygen activated by “naked” or ligated metals? Details of the potential energy surfaces of the three representative cations [Fe,O2]+, [Cr,O2]+, and [CH3Re(O2)2O]+ were correlated with mass spectrometric data. The results may lead to a better understanding of O2 activation in synthetic, industrial, and biological processes. Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：2517 / 2520

页数：4

共 45 条

[41] SIOH+/HSIO+ AND SIOH./HSIO. - GAS-PHASE GENERATION AND CHARACTERIZATION - A COMBINED NEUTRALIZATION REIONIZATION MASS-SPECTROMETRY AND ABINITIO MOLECULAR-ORBITAL STUDY [J].