MOLECULAR MOSAICS FORMED BY A SQUARE CYCLOPHANE AND ITS INCLUSION COMPLEX WITH FERROCENE

被引:54
作者
ASHTON, PR
CLAESSENS, CG
HAYES, W
MENZER, S
STODDART, JF
WHITE, AJP
WILLIAMS, DJ
机构
[1] UNIV BIRMINGHAM, SCH CHEM, BIRMINGHAM B15 2TT, W MIDLANDS, ENGLAND
[2] UNIV LONDON IMPERIAL COLL SCI & TECHNOL, CHEM CRYSTALLOG LAB, LONDON, ENGLAND
[3] ECOLE NORMALE SUPER, LYON, FRANCE
关键词
HOST-GUEST CHEMISTRY; NANOTUBES; SANDWICH COMPLEXES; SELF-ASSEMBLY;
D O I
10.1002/anie.199518621
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Highly ordered two‐dimensional sheets sustained by π‐donor/π‐acceptor interactions and the ability to form an inclusion complex with ferrocene with only minimal changes in crystal packing are the outstanding features of the macrocyclic tetracation 1. This cyclophane can be prepared in two steps from bipyridine and the dibromide 2. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany
引用
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页码:1862 / 1865
页数:4
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