MONO-ETA-CYCLOPENTADIENYL-BENZAMIDINATO CHLORO COMPOUNDS OF TITANIUM, ZIRCONIUM AND HAFNIUM

被引：89

作者：

GOMEZ, R

DUCHATEAU, R

CHERNEGA, AN

TEUBEN, JH

EDELMANN, FT

GREEN, MLH

机构：

[1] UNIV OXFORD, INORGAN CHEM LAB, OXFORD OX1 3QR, ENGLAND

[2] UNIV GRONINGEN, DEPT CHEM, 9747 AG GRONINGEN, NETHERLANDS

[3] UNIV GOTTINGEN, INST ANORGAN CHEM, D-37077 GOTTINGEN, GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 491卷 / 1-2期

关键词：

TITANIUM; ZIRCONIUM; HAFNIUM; ETA-CYCLOPENTADIERYL; BENZAMIDINATO; ZIEGLER-NATTA;

D O I：

10.1016/0022-328X(94)05237-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The new compounds {M(eta-C(5)R(5))[eta-CPh(NSiMe(3))(2)]]Cl-2} (where R = H, M = Ti, Zr, Hf or R = Me, M = Ti or Zr), are described. The crystal structures of {M(eta-C(5)R(5))([eta-CPh(NSiMe(3))(2)]Cl-2} (R = H, M = Zr or Hf) have been determined. The compound {Zr(eta-C5H5)[eta-CPh(NSiMe(3))(2)]Cl-2} acts as a co-catalyst for the polymerisation of ethylene and propene.

引用

页码：153 / 158

页数：6

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