INTERMEDIATE PRODUCT YIELD ENHANCEMENT WITH A CATALYTIC INORGANIC MEMBRANE .1. ANALYTICAL MODEL FOR THE CASE OF ISOTHERMAL AND DIFFERENTIAL OPERATION

A simple model is developed to examine the performance of a supported catalytic membrane within which occurs the consecutive-parallel reaction system given by A + B --> R, with rate = k1p(A)alphaA1p(B)alphaB, and A + R --> P, with rate = k2p(A)alphaA2p(R)alphaR. Closed-form solutions reveal that segregation of reactants A and B to opposite sides of the membrane''is an effective strategy for increasing the desired product (R) point yield. However, increases in the component R yield come at the expense of the point catalyst utilization, due, in part, to depletion of reacting components B and R. The membrane performance is sensitive to the relative reaction orders with respect to component A for the special case in which the rates are zeroth-order with respect to B and R (alpha(B) = alpha(R) = 0). The segregation strategy is shown to be most beneficial if three requirements are met: (i) alpha(A1) < alpha(A2), (ii) k1, k2 sufficiently large and (iii) active layer sufficiently thin compared to support. Under favorable conditions [requirements (i)-(iii) met], component R is selectively produced near the active layer surface, and diffuses out of the membrane before further reaction to undesired product (P). The simulations indicate that the fractional increases in the R yield attained, as the degree of segregation is increased, exceed the fractional decreases in catalyst utilization. A secondary benefit of the membrane design is the confinement of reaction products in the bulk stream on the active layer side, thus reducin the downstream se ration needs.