ALLYLATION AND [3+2]-CYCLOADDITION REACTIONS OF IMINES WITH ALLYL(CYCLOPENTADIENYL)IRON(II) DICARBONYL COMPLEXES

被引：14

作者：

CHEN, T ^{[1
]}

JIANG, SC ^{[1
]}

TUROS, E ^{[1
]}

机构：

[1] SUNY BUFFALO, DEPT CHEM, BUFFALO, NY 14260 USA

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 45期

关键词：

LEWIS ACID-PROMOTED ADDITION; ALLYL(CYCLOPENTADIENYL)IRON(II) DICARBONYL COMPLEXES; IMINE ALLYLATION; PYRROLIDINES; IRON-OLEFIN PI-COMPLEXES;

D O I：

10.1016/S0040-4039(00)74398-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Allyl(cyclopentadienyl)iron(II) dicarbonyl (I) reads with N-tosylimines to give either iron-olefin complexes 2 or pyrrolidines 3, depending on the quantity and nature of the Lewis acid and the work-up procedure.

引用

页码：8325 / 8328

页数：4

共 33 条

[1] LEWIS ACID-PROMOTED ADDITION OF ALLYL(CYCLOPENTADIENYL)IRON(II) DICARBONYL TO ALDEHYDES - A NEW ALDEHYDE ALLYLATION METHOD [J].

AGOSTON, GE ;

CABAL, MP ;

TUROS, E .

TETRAHEDRON LETTERS, 1991, 32 (26) :3001-3004

[2] INDIUM-MEDIATED ALLYLATION OF ALDIMINES [J].

BEUCHET, P ;

LEMARREC, N ;

MOSSET, P .

TETRAHEDRON LETTERS, 1992, 33 (40) :5959-5960

[3] DIASTEREOSELECTIVE ALLYLATION OF CHIRAL IMINES - NOVEL APPLICATION OF ALLYLCOPPER REAGENTS TO THE ENANTIOSELECTIVE SYNTHESIS OF HOMOALLYL AMINES [J].

BOCOUM, A ;

BOGA, C ;

SAVOIA, D ;

UMANIRONCHI, A .

TETRAHEDRON LETTERS, 1991, 32 (10) :1367-1370

[4] PREPARATION OF ACTIVATED IMINES AND THEIR CONDENSATION WITH ALLYLSTANNANES - STEREOSELECTIVE SYNTHESIS OF 1,2-AMINO ALCOHOLS [J].

CIUFOLINI, MA ;

SPENCER, GO .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (20) :4739-4741

[5] STERICALLY HINDERED REACTIONS OF GRIGNARD REAGENTS WITH SCHIFF BASES [J].

EMLING, BL ;

HORVATH, RJ ;

SARACENO, AJ ;

ELLERMEYER, EF ;

HAILE, L ;

HUDAC, LD .

JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (05) :657-660

[6] A MODIFICATION OF THE HIYAMA REACTION - SYNTHESIS OF HOMO ALLYLIC AMINES FROM IMINES AND ALLYLIC BROMIDES IN THE PRESENCE OF CRCL2 [J].

GIAMMARUCO, M ;

TADDEI, M ;

ULIVI, P .

TETRAHEDRON LETTERS, 1993, 34 (22) :3635-3638

[7] ALLYL AND OLEFIN COMPLEXES OF IRON [J].

GREEN, MLH ;

NAGY, PLI .

JOURNAL OF THE CHEMICAL SOCIETY, 1963, (JAN) :189-+

[8] DIASTEREOGENIC ADDITION OF CROTYLMETAL COMPOUNDS TO ALDEHYDES [J].

HOFFMANN, RW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1982, 21 (08) :555-566

[9] LEWIS ACID-PROMOTED ADDITION OF ALLYL(CYCLOPENTADIENYL)IRON(II) DICARBONYL TO UNACTIVATED KETONES [J].

JIANG, SC ;

TUROS, E .

TETRAHEDRON LETTERS, 1991, 32 (36) :4639-4642

[10] [3+2]-CYCLOADDITION REACTIONS OF ALLYL(CYCLOPENTADIENYL)IRON(II) DICARBONYL WITH UNACTIVATED CARBONYL-COMPOUNDS [J].

JIANG, SC ;

TUROS, E .

ORGANOMETALLICS, 1993, 12 (11) :4280-4282

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