METAL-COMPLEXES WITH TETRAPYRROLE LIGANDS .57. SYNTHESIS, SPECTRA, AND STRUCTURE OF NITRIDORHENIUM(V) PORPHYRINS

被引：24

作者：

BUCHLER, JW ^{[1
]}

DECIAN, A ^{[1
]}

FISCHER, J ^{[1
]}

KRUPPA, SB ^{[1
]}

WEISS, R ^{[1
]}

机构：

[1] UNIV STRASBOURG 1,CRISTALLOCHIM & CHIM STRUCT LAB,CNRS,UA 424,F-67070 STRASBOURG,FRANCE

来源：

CHEMISCHE BERICHTE | 1990年 / 123卷 / 12期

关键词：

RHENIUM(V) PORPHYRINS; NITRIDORHENIUM(V) COMPLEXES; RHENIUM-NITROGEN TRIPLE BONDS; METALLOPORPHYRINS;

D O I：

10.1002/cber.19901231204

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Oxorhenium(V) porphyrins ReO(P)X (X = Cl, Br) or [ReO(P)]2O, or trichlororhenium (V) porphyrins ReCl3(P) (P = OEP, TPP, TTP, TAP, TClP, TMP)2,3), respectively, are transformed into nitridorhenium(V) porphyrins ReN(P) with hydrazine hydrate in the presence of ethanol, in good yields. The diamagnetic complexes are stable towards hydrolysis and contain pentacoordinate Re(V) in a square pyramid of nitrogen donor atoms. Their structure is deduced spectrometrically and is proven in the case of ReN(OEP) by X-ray crystallography. The UV/Vis- and H-1-NMR spectra of the new nitrido complexes are compared with those of the corresponding zinc(II) porphyrins.

引用

页码：2247 / 2253

页数：7

共 61 条

[41] PEROXOTITANIUM(IV) PORPHYRINS - SYNTHESIS, STEREOCHEMISTRY, AND PROPERTIES [J].

GUILARD, R ;

LATOUR, JM ;

LECOMTE, C ;

MARCHON, JC ;

PROTAS, J ;

RIPOLL, D .

INORGANIC CHEMISTRY, 1978, 17 (05) :1228-1237

[42] STRUCTURAL CHARACTERIZATION OF A COMPLEX OF MANGANESE(V) - NITRIDO[TETRAKIS(PARA-METHOXYPHENYL)PORPHINATO]-MANGANESE(V) [J].

HILL, CL ;

HOLLANDER, FJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1982, 104 (25) :7318-7319

[43]

HOARD JL, 1975, PORPHYRINS METALLOPO, P326

[44]

Janson TR, 1979, PORPHYRINS B, VIV, P1

[45]

KNORR G, 1989, THESIS U TUBINGEN

[46] INVESTIGATION OF THE SYNTHESIS OF ORTHO-SUBSTITUTED TETRAPHENYLPORPHYRINS [J].

LINDSEY, JS ;

WAGNER, RW .

JOURNAL OF ORGANIC CHEMISTRY, 1989, 54 (04) :828-836

[47]

LINDSEY JS, 1987, TETRAHEDRON LETT, V27, P3069

[48]

MEUNIER B, 1986, B SOC CHIM FR, V2, P578

[49] CRYSTAL AND MOLECULAR-STRUCTURE OF 2,3,7,8,12,13,17,18-OCTAETHYLPORPHINATOOXOVANADIUM(IV) [J].

MOLINARO, FS ;

IBERS, JA .

INORGANIC CHEMISTRY, 1976, 15 (09) :2278-2283

[50]

MRVA A, 1988, CRYST RES TECHNOL, V23, P773

← 1 2 3 4 5 6 7 →