STRUCTURES OF BIS(DI-2-PYRIDYLAMINE)DI-NITRATOCOPPER(II) AND BIS(ACETATO)BIS(DI-2-PYRIDYLAMINE)COPPER(II) MONOHYDRATE

被引：19

作者：

MUNOZ, MC ^{[1
]}

LAZARO, JM ^{[1
]}

FAUS, J ^{[1
]}

JULVE, M ^{[1
]}

机构：

[1] UNIV VALENCIA,FAC QUIM,DEPT QUIM INORGAN,E-46100 BURJASSOT,SPAIN

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193002859

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Both complexes consist of neutral mononuclear units, the copper(II) environment being distorted 4 + 2 octahedral for (I) and distorted square pyramidal for (II). Compound (I) is centrosymmetric. Its equatorial plane comprises the four N atoms of two di-2-pyridylamine (dpyam) ligands with the axial positions filled by two O atoms of two unidentate nitrate anions. The equatorial plane in (II) is composed of the two N atoms of dpyam and two O atoms of two acetate groups, with the apical position occupied by another O atom of one of the acetate ligands. A structural comparison is made with other dpyam-containing copper(II) complexes and the influence of the counterion is discussed.

引用

页码：1756 / 1761

页数：6

共 26 条

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