VIBRATION-SPECTRA AND NORMAL-COORDINATE ANALYSIS OF DI-TERT-BUTYLSILANES (T)BU(2)SIX(3), X=H, D, F, CL, BR, I

被引：4

作者：

HASSLER, K ^{[1
]}

WEIDENBRUCH, M ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,W-2900 OLDENBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期

关键词：

SILANE; INFRARED SPECTROSCOPY; RAMAN SPECTROSCOPY;

D O I：

10.1016/0022-328X(94)87047-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The infrared and Raman vibrational spectra of the di-t-butylsilanes (t)Bu(2)SiX(2) (X = H, D, F, CI, Br, I) were recorded. Using a local symmetry force field for the t-butyl groups, normal coordinate analyses have been performed. To study the behaviour of t-butyl groups when the symmetry is lower than C-3 nu, the spectra of (t)BuSiI(2)H and (t)BuSiBr(2)H were included in the calculations.

引用

页码：137 / 144

页数：8

共 15 条

[1]

BALL DF, 1960, SPECTROCHIM ACTA, V16, P1358

[2]

Califano S., 1976, VIBRATIONAL STATES

[3] HINDERED ORGANOSILICON COMPOUNDS - SYNTHESIS AND PROPERTIES OF DI-TERT-BUTYLSILANE, DI-TERT-BUTYLMETHYLSILANE, AND TRI-TERT-BUTYLSILANES [J].

DOYLE, MP ;

WEST, CT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (13) :3777-3782

[4] DETERMINATION OF THE GAS-PHASE MOLECULAR-STRUCTURES OF DI-TERT-BUTYLDICHLOROSILANE AND DI-TERT-BUTYLCHLOROSILANE BY ELECTRON-DIFFRACTION AND MOLECULAR MECHANICS CALCULATIONS [J].

FORSYTH, GA ;

RANKIN, DWH .

JOURNAL OF MOLECULAR STRUCTURE, 1990, 222 (3-4) :467-478

[5] VIBRATIONAL-SPECTRA OF SOME BIS(TRIDEUTEROMETHYL)SILANES (CD3)2SIX2 (X=H,F,CL,BR,J,PH) AND THEIR USE IN CALCULATING VALENCE FORCE-CONSTANTS [J].

HASSLER, K .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1981, 37 (07) :511-518

[6] VIBRATION-SPECTRA, NORMAL-COORDINATE ANALYSIS AND SYNTHESIS OF TERT-BUTYLSILANES (T)BUSIX(3), X=H, D, F, CL, BR, I [J].

HASSLER, K ;

WEIDENBRUCH, M .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 465 (1-2) :127-135

[7] NORMALKOORDINATENANALYSE UND BERECHNUNG VON KRAFTKONSTANTEN AN DEN TERTIARBUTYLHALOGENIDEN [J].

HUTTNER, W ;

ZEIL, W .

SPECTROCHIMICA ACTA, 1966, 22 (06) :1007-&

[8]

SCHAFER A, 1984, ANGEW CHEM, V96, P311

[9]

TSUMURAYA T, 1991, ANGEW CHEM, V103, P916

[10]

TYLER LJ, 1977, J AM CHEM SOC, V70, P9

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