VIBRATION-SPECTRA, NORMAL-COORDINATE ANALYSIS AND SYNTHESIS OF TERT-BUTYLSILANES (T)BUSIX(3), X=H, D, F, CL, BR, I

被引：6

作者：

HASSLER, K ^{[1
]}

WEIDENBRUCH, M ^{[1
]}

机构：

[1] UNIV OLDENBURG,FACHBEREICH CHEM,W-2900 OLDENBURG,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 465卷 / 1-2期

关键词：

SILANE; INFRARED SPECTROSCOPY; RAMAN SPECTROSCOPY;

D O I：

10.1016/0022-328X(94)87046-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The infrared and Raman vibrational spectra of the t-butylsilanes (t)BuSiX(3) (X = H, D, F, CI, Br, I) have been measured and assigned with the aid of normal coordinate analyses. The SiX valence-force constants that were calculated are somewhat smaller than the values for the silanes SiX(4). A number of t-butylsilanes were prepared using new reaction pathways and new precursor molecules, whose properties are described.

引用

页码：127 / 135

页数：9

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