OPTIMAL-CONTROL OF MOLECULAR-DYNAMICS VIA 2-PHOTON PROCESS

被引：17

作者：

YAN, YJ ^{[1
]}

机构：

[1] UNIV CALIF SAN DIEGO,INST NONLINEAR SCI,LA JOLLA,CA 92093

来源：

JOURNAL OF CHEMICAL PHYSICS | 1994年 / 100卷 / 02期

关键词：

D O I：

10.1063/1.466641

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The theory of optimal control of molecular dynamics via a two-photon process is developed in terms of the density matrix in Liouville space. Applications are made to the generalized Tannor-Rice pump-dump molecular control scheme involving two and three electronic states. The solutions of two coupled eigenequations directly give the optimal pump and dump control fields with respect to the target. The globally optimal solutions are analyzed and the numerical implementation is discussed. Formal comparisons with pump-probe (chi((3))) optical processes are also given.

引用

页码：1094 / 1102

页数：9

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