SYNTHESIS, CRYSTAL-STRUCTURE AND SOME DERIVATIVES OF THE CHLOROTRIS(TETRAMETHYLPHOSPHOLYL)URANIUM

被引：33

作者：

GRADOZ, P

BOISSON, C

BAUDRY, D

LANCE, M

NIERLICH, M

VIGNER, J

EPHRITIKHINE, M

机构：

[1] CEA,CE SACLAY,CHIM URANIUM LAB,F-91191 GIF SUR YVETTE,FRANCE

[2] CEA,CE SACLAY,SERV CHIM MOLEC LAB,CRISTALLOG LAB,CNRS,URA,F-91191 GIF SUR YVETTE,FRANCE

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 23期

关键词：

D O I：

10.1039/c39920001720

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of UCl4 with the potassium salt of the tetramethylphospholyl anion afforded the title compound, which has been transformed into the derivatives [U(eta-C4Me4P)3X] (X = H, Me, OPr(i)); the trigonal crystal structure revealed that the three phospholyl ligands are pentahapto bonded to the uranium.

引用

页码：1720 / 1721

页数：2

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