SILVER ION-SELECTIVE EXTRACTION WITH DITHIAZACROWN, TETRATHIAZACROWN, AND TETRATHIADIAZACROWN ETHER DERIVATIVES

被引：26

作者：

SAKAMOTO, H

ISHIKAWA, J

OTOMO, M

机构：

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1995年 / 68卷 / 10期

关键词：

D O I：

10.1246/bcsj.68.2831

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Dithiazacrown, tetrathiazacrown, and two tetrathiadiazacrown ether derivatives, bearing a phenyl group on each nitrogen atom at the periphery, were synthesized, and the solvent extractions of some transition metal ions with these compounds were carried out using an H2O-1,2-dichloroethane system. All of the thiazacrown compounds employed exhibited Ag+ selectivity, and formed 1:1:1 complexes of Ag+:ligand:laurate ion as a counter anion to be extracted into a 1,2-dichloroethane solution. The extractabilities (extraction constants, K-ex) fdr Ag+ decreased in the order: 7,16-diphenyltetrathia-7,16-diaza-18-crow-6 (3) (log K-ex=1.18+/-0.13)>13-phenyltetrathia-13-aza-15-crown-5 (2) (0.75+/-0.09)>7-phenyldithia-7-aza-9-crown-3 (1) (-0.47+/-0.06)>13, 16-diphenyltetrathia-13,16-diaza-18-crown-6 (4) (-0.62+/-0.16).

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页码：2831 / 2836

页数：6

相关论文

共 29 条

[1] METAL-ION RECOGNITION - DONOR-SET CONTROL OF SILVER(I)/LEAD(II) DISCRIMINATION USING MIXED-DONOR MACROCYCLIC LIGANDS [J].

ADAM, KR ;

BALDWIN, DS ;

BASHALL, A ;

LINDOY, LF ;

MCPARTLIN, M ;

POWELL, HR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1994, (02) :237-238

[2] STRUCTURAL ISOMERISM IN SILVER THIOETHER MACROCYCLIC CHEMISTRY - THE SYNTHESIS, REDOX PROPERTIES AND CRYSTAL-STRUCTURES OF [AGN([15]ANES5)N][PF6]N, [AG2([15]ANES5)2][BPH4]2 AND [AG([15]ANES5)][B(C6F5)4] ([15]ANES5=1,4,7,10,13-PENTATHIACYCLOPENTADECANE) [J].

BLAKE, AJ ;

COLLISON, D ;

GOULD, RO ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (04) :521-531

[3] SILVER MACROCYCLIC COMPLEXES - SYNTHESIS, CRYSTAL-STRUCTURES AND REDOX PROPERTIES OF [AG([18]ANEN2S4)]PF6 AND [AG(ME2[18]ANEN2S4)]BPH4([18]ANEN2S4=1,4,10,13-TETRATHIA-7,16-DIAZACYCLOOCTADECANE, ME2[18]ANEN2S4=7,16-DIMETHYL-1,4,10,13-TETRATHIA-7,16-DIAZACYCLOOCTADECANE) [J].

BLAKE, AJ ;

REID, G ;

SCHRODER, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, :615-620

[4] CHEMISTRY OF THIOETHER MACROCYCLIC COMPLEXES [J].

Blake, Alexander J. ;

Schroeder, Martin .

ADVANCES IN INORGANIC CHEMISTRY <D>, 1990, 35 :1-80

[5] FUNCTIONALIZED DITHIA-CROWNS AND TETRATHIA-CROWNS AND THEIR USE TO QUANTITATIVELY SEPARATE AND RECOVER GOLD(III), PALLADIUM(II), SILVER(I) AND MERCURY(II) IONS [J].

BRADSHAW, JS ;

KRAKOWIAK, KE ;

IZATT, RM ;

BRUENING, RL ;

TARBET, BJ .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1990, 27 (02) :347-349

[6] QUANTITATION OF CATION BINDING BY SILICA-GEL BOUND THIAMACROCYCLES AND THE DESIGN OF HIGHLY SELECTIVE CONCENTRATION AND PURIFICATION COLUMNS FOR PALLADIUM(II), GOLD(III), SILVER(I), AND MERCURY(II) [J].

BRUENING, RL ;

TARBET, BJ ;

KRAKOWIAK, KE ;

BRUENING, ML ;

IZATT, RM ;

BRADSHAW, JS .

ANALYTICAL CHEMISTRY, 1991, 63 (10) :1014-1017

[7] CHEMICALLY MODIFIED FIELD-EFFECT TRANSISTORS - POTENTIOMETRIC AG+ SELECTIVITY OF PVC MEMBRANES BASED ON MACROCYCLIC THIOETHERS [J].

BRZOZKA, Z ;

COBBEN, PLHM ;

REINHOUDT, DN ;

EDEMA, JJH ;

BUTER, J ;

KELLOGG, RM .

ANALYTICA CHIMICA ACTA, 1993, 273 (1-2) :139-144

[8] SYNTHESIS OF SULFUR-CONTAINING MACROCYCLES USING CESIUM THIOLATES [J].

BUTER, J ;

KELLOGG, RM .

JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (22) :4481-4485

[9] 1,4,7-TRIOXA-10-AZACYCLODODECANE AND SOME N-SUBSTITUTED DERIVATIVES - SYNTHESIS AND CATION COMPLEXING [J].

CALVERLEY, MJ ;

DALE, J .

ACTA CHEMICA SCANDINAVICA SERIES B-ORGANIC CHEMISTRY AND BIOCHEMISTRY, 1982, 36 (04) :241-247

[10] SILVER(I) ION-SELECTIVE ELECTRODES BASED ON POLYTHIA-MACROCYCLES [J].

CASABO, J ;

MESTRES, L ;

ESCRICHE, L ;

TEIXIDOR, F ;

PEREZJIMENEZ, C .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (08) :1969-1971