1,4-DIOXENE IN ORGANIC-SYNTHESIS - AN APPROACH TO THE A,B RING-SYSTEM OF FORSKOLIN

被引：13

作者：

BLANCHOTCOURTOIS, V ^{[1
]}

FETIZON, M ^{[1
]}

HANNA, I ^{[1
]}

机构：

[1] ECOLE POLYTECH,CNRS,SYNTHESE ORGAN LAB,F-91128 PALAISEAU,FRANCE

来源：

TETRAHEDRON LETTERS | 1992年 / 33卷 / 35期

关键词：

1,4-DIOXENE; FORSKOLIN; INTRAMOLECULAR DIELS-ALDER REACTION; ALLYLIC HYDROXYLATION;

D O I：

10.1016/S0040-4039(00)61189-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A methodology for the introduction of C-6 and C-7 oxygenated groups in the AB ring system of forskolin based on the use of 1,4-dioxene is reported.

引用

页码：5061 / 5064

页数：4

共 12 条

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[6] THE CHEMISTRY OF 1,4-DIOXENE (2,3-DIHYDRO-1,4-DIOXIN) .8.
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[7] 1,4-DIOXENE IN ORGANIC-SYNTHESIS .6. SUBSTITUTED 2-VINYL-1,4-DIOXENES - USEFUL INTERMEDIATES FOR THE SYNTHESIS OF HIGHLY FUNCTIONALIZED COMPOUNDS
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PRANGE, T
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (24) : 5672 - 5679
[8] A TOTAL SYNTHESIS OF (+/-)-FORSKOLIN
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SAKATA, S
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IKEGAMI, S
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (11) : 3670 - 3672
[9] HASHIMOTO S, 1991, TETRAHEDRON LETT, V32, P4025
[10] AN INTRAMOLECULAR DIELS-ALDER APPROACH TO FORSKOLIN
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