SELECTIVE CONVERSION OF NITROBENZENE TO PHENYLCARBAMATES CATALYZED BY PD(II) AND HETEROPOLYACIDS

被引:12
作者
LEE, JS
WOO, JW
LEE, CW
HONG, KS
YEO, JK
机构
[1] Department of Chemical Engineering, Pohang Institute of Science and Technology, Pohang
[2] Lucky Central Research Institute, Daejeon, Science Town
关键词
D O I
10.1007/BF02705060
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A homogeneous catalyst system of Pd(ll) and a heteropolyacid (HPA) converts nitrobenzene to N-phenylcarbamate with a selectivity of 96.3% at 100% nitrobenzene conversion, which appears to be the best value known in the literature. However, the catalyst forms solid deposits during the reaction. © 1990 Korean Institute of Chemical Engineering.
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收藏
页码:145 / 147
页数:3
相关论文
共 11 条
  • [1] Ozaki S., Chem. Rev., 72, (1972)
  • [2] Cenini S., Crotti C., Pizzotti M., Porta F., J. Org. Chem., 53, (1988)
  • [3] Halligudi S.B., Chaudhari R.B., Doraiswamy L.K., Carbonylation of nitrobenzene to phenyl isocyanate using palladium complex catalysts. Screening of catalysts and kinetic study, Industrial & Engineering Chemistry Process Design and Development, 23, (1984)
  • [4] Gupte S.B., Chaudhari R.B., J. Mol. Catal., 34, (1986)
  • [5] Alessio E., Mestroni G., J. Organometallic Chem., 291, (1985)
  • [6] Fukuoka S., Chono M., Kohno M., J. Org. Chem., 49, (1984)
  • [7] Mateev K.I., Zhighina E.G., Shitova N.R., Kuznetsova L.I., Kinet. Katal., 18, (1977)
  • [8] Misono M., Chemistry and Uses of Molybdenum, (1982)
  • [9] Golodov V.A., Jumakaeva B.S., J. Mol. Catai, 35, (1986)
  • [10] Rocchiccioli-Deltcheff C., Thouvenot R., Franck R., Spectrochim. Acta, 32 A, (1976)