SELECTIVE CONVERSION OF NITROBENZENE TO PHENYLCARBAMATES CATALYZED BY PD(II) AND HETEROPOLYACIDS

被引:12
作者
LEE, JS
WOO, JW
LEE, CW
HONG, KS
YEO, JK
机构
[1] Department of Chemical Engineering, Pohang Institute of Science and Technology, Pohang
[2] Lucky Central Research Institute, Daejeon, Science Town
关键词
D O I
10.1007/BF02705060
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A homogeneous catalyst system of Pd(ll) and a heteropolyacid (HPA) converts nitrobenzene to N-phenylcarbamate with a selectivity of 96.3% at 100% nitrobenzene conversion, which appears to be the best value known in the literature. However, the catalyst forms solid deposits during the reaction. © 1990 Korean Institute of Chemical Engineering.
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收藏
页码:145 / 147
页数:3
相关论文
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  • [11] Fruchart J.M., Herve G., Launay J.P., Massart R., J. Inorg. Nucl. Chem., 38, (1976)