THE STRUCTURES OF SOLVENT-SEPARATED NAPHTHALENE AND ANTHRACENE RADICAL-ANIONS

被引：47

作者：

BOCK, H

ARAD, C

NATHER, C

HAVLAS, Z

机构：

[1] Department of Chemistry, University of Frankfurt, D-60439 Frankfurt/Main

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 23期

关键词：

D O I：

10.1039/C39950002393

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduction of naphthalene and anthracene in diglyme, a thermodynamically favourable chelate ether for Na+ solvation, with sodium metal gave the crystalline solvent-separated radical anion salts, [C10H8.-][Na+(diglyme)(2)] and [C14H10.-][Na+(diglyme)(2)] whose structures were determined.

引用

收藏

页码：2393 / 2394

页数：2

相关论文

共 21 条

[1] CRYSTALLIZATION AND STRUCTURE OF ((H53C44O43-)[LI-6(+)(NH3)(2)]((O4C44H53)-O-3-)), AN EDGE-SHARED LI-6(+) DOUBLE TETRAHEDRON BETWEEN CALIX[4]ARENETRIANION HALF-SHELLS - ANOTHER SELF-ORGANIZED AND PIPOPHILICALLY-WRAPPED POLYION AGGREGATE [J].

BOCK, H ;

JOHN, A ;

NATHER, C ;

HAVLAS, Z .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (36) :9367-9368

[2] THE TRIPLET BIRADICAL TRIS(3,5-DI-TERT-BUTYL-4-OXOPHENYLENE)METHANE - CRYSTAL-STRUCTURE, AND SPIN AND CHARGE-DISTRIBUTION [J].

BOCK, H ;

JOHN, A ;

HAVLAS, Z ;

BATS, JW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (03) :416-418

[3] DISTORTED MOLECULES - PERTURBATION DESIGN, PREPARATION AND STRUCTURES [J].

BOCK, H ;

RUPPERT, K ;

NATHER, C ;

HAVLAS, Z ;

HERRMANN, HF ;

ARAD, C ;

GOBEL, I ;

JOHN, A ;

MEURET, J ;

NICK, S ;

RAUSCHENBACH, A ;

SEITZ, W ;

VAUPEL, T ;

SOLOUKI, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1992, 31 (05) :550-581

[4] SINGLE-CRYSTAL STRUCTURE OF THE SOLVENT-SEPARATED RADICAL-ION PAIR [9,10-DIPHENYLANTHRACENE(CENTER-DOT)CIRCLE-MINUS][NA-CIRCLE-PLUS(THF)(6)] AND ITS IMPLICATION FOR CATION SOLVATION [J].

BOCK, H ;

JOHN, A ;

NATHER, C ;

HAVLAS, Z ;

MIHOKOVA, E .

HELVETICA CHIMICA ACTA, 1994, 77 (01) :41-50

[5] SOME STATIC ASPECTS OF MOLECULAR SELF-ORGANIZATION FROM SINGLE-CRYSTAL STRUCTURAL DATA [J].

BOCK, H .

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1994, 240 :155-168

[6] ELECTRON-TRANSFER AND ION-PAIR FORMATION .34. SINGLE-CRYSTAL STRUCTURE OF THE SOLVENT-SEPARATED ION-PAIR [9,9'-BIANTHRYL-CENTER-DOT-CIRCLE-MINUS] [NA-CIRCLE-PLUS(DME)(3)] [J].

BOCK, H ;

JOHN, A ;

NATHER, C ;

HAVLAS, Z .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1994, 49 (10) :1339-1347

[7]

BOCK H, 1994, ANGEW CHEM INT EDIT, V32, P875

[8]

BOCK H, 1994, ACTA NOVA LEOPOLDINA, V38, P221

[9]

BOCK H, 1992, ANGEW CHEM, V104, P564

[10]

BOCK H, 1993, J AM CHEM SOC, V114, P6907