METHANOL REDUCES AN ORGANOPALLADIUM(II) COMPLEX TO A PALLADIUM(I) HYDRIDE - CRYSTALLOGRAPHIC CHARACTERIZATION OF A HYDRIDO-BRIDGED PALLADIUM COMPLEX

被引：80

作者：

PORTNOY, M ^{[1
]}

FROLOW, F ^{[1
]}

MILSTEIN, D ^{[1
]}

机构：

[1] WEIZMANN INST SCI,DEPT ORGAN CHEM,IL-76100 REHOVOT,ISRAEL

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 12期

关键词：

D O I：

10.1021/om00058a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The organopalladium(II) complex 1 is reduced by methanol to the hydrido-bridged Pd(I) complex 2, which was crystallographically characterized. A mechanism involving electrophilic attack of a cationic palladium hydride intermediate on a Pd(0) carbonyl complex is indicated.

引用

页码：3960 / 3962

页数：3

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