METHANOL REDUCES AN ORGANOPALLADIUM(II) COMPLEX TO A PALLADIUM(I) HYDRIDE - CRYSTALLOGRAPHIC CHARACTERIZATION OF A HYDRIDO-BRIDGED PALLADIUM COMPLEX

被引：80

作者：

PORTNOY, M ^{[1
]}

FROLOW, F ^{[1
]}

MILSTEIN, D ^{[1
]}

机构：

[1] WEIZMANN INST SCI,DEPT ORGAN CHEM,IL-76100 REHOVOT,ISRAEL

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 12期

关键词：

D O I：

10.1021/om00058a007

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The organopalladium(II) complex 1 is reduced by methanol to the hydrido-bridged Pd(I) complex 2, which was crystallographically characterized. A mechanism involving electrophilic attack of a cationic palladium hydride intermediate on a Pd(0) carbonyl complex is indicated.

引用

页码：3960 / 3962

页数：3

共 26 条

[21] MIXED-METAL CLUSTERS VIA METAL HYDRIDE COUPLING - NEW RHENIUM-OSMIUM CLUSTERS AND CRYSTAL-STRUCTURE OF H2RE2OS3(CO)20 [J].

SHAPLEY, JR ;

PEARSON, GA ;

TACHIKAWA, M ;

SCHMIDT, GE ;

CHURCHILL, MR ;

HOLLANDER, FJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (24) :8064-8065

[22] PROTONATION OF PHOSPHINE COMPLEXES OF ZEROVALENT NICKEL, PALLADIUM, PLATINUM, AND RUTHENIUM WITH FLUOROCARBON ACIDS [J].

SIEDLE, AR ;

NEWMARK, RA ;

GLEASON, WB .

INORGANIC CHEMISTRY, 1991, 30 (09) :2005-2009

[23]

Tsuji J., 1980, ORGANIC SYNTHESIS PA

[24]

YAMAMOTO A, 1985, ORGANOTRANSITION ETA, P240

[25] SYNTHESIS AND REACTIONS OF DINUCLEAR PALLADIUM COMPLEXES CONTAINING METHYLS AND HYDRIDE ON ADJACENT PALLADIUM CENTERS - REDUCTIVE ELIMINATION AND CARBONYLATION REACTIONS [J].

YOUNG, SJ ;

KELLENBERGER, B ;

REIBENSPIES, JH ;

HIMMEL, SE ;

MANNING, M ;

ANDERSON, OP ;

STILLE, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (17) :5744-5753

[26] FORMATION AND REACTIVITY OF PALLADIUM HYDRIDE COMPLEXES, [(PPH3)3PDH]+ AND "[(PPH3)2PD(MU-H)(MU-CO)PD(PPH3)2]+, IN AQUEOUS TRIFLUOROACETIC-ACID SOLUTIONS [J].

ZUDIN, VN ;

CHINAKOV, VD ;

NEKIPELOV, VM ;

LIKHOLOBOV, VA ;

YERMAKOV, YI .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1985, 289 (2-3) :425-430

← 1 2 3 →