METHYLTRIOXORHENIUM-CATALYZED C-H INSERTION REACTIONS OF HYDROGEN-PEROXIDE

被引：89

作者：

MURRAY, RW ^{[1
]}

IYANAR, K ^{[1
]}

CHEN, JX ^{[1
]}

WEARING, JT ^{[1
]}

机构：

[1] PULP & PAPER RES INST CANADA,VANCOUVER LAB,VANCOUVER,BC V6S 2L9,CANADA

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 36期

关键词：

D O I：

10.1016/0040-4039(95)01344-H

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Methyltrioxorhenium catalyzes the C-H insertion reaction of hydrocarbons by hydrogen peroxide. In suitable substrates the reaction is stereospecific with retention.

引用

页码：6415 / 6418

页数：4

共 10 条

[1] OXIDATIONS OF ER(3) (E=P, AS, OR SB) BY HYDROGEN-PEROXIDE - METHYLRHENIUM TRIOXIDE AS CATALYST [J].

ABUOMAR, MM ;

ESPENSON, JH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (01) :272-280

[2] CATALYTIC-OXIDATION OF PHENOLS TO P-QUINONES WITH THE HYDROGEN-PEROXIDE AND METHYLTRIOXORHENIUM(VII) SYSTEM [J].

ADAM, W ;

HERRMANN, WA ;

LIN, JH ;

SAHAMOLLER, CR .

JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (26) :8281-8283

[3] CHEMOSELECTIVE METHYLTRIOXORHENIUM(VII)-CATALYZED SULFOXIDATIONS WITH HYDROGEN-PEROXIDE [J].

ADAM, W ;

MITCHELL, CM ;

SAHAMOLLER, CR .

TETRAHEDRON, 1994, 50 (46) :13121-13124

[4]

ADAM W, 1994, ANGEW CHEM INT EDIT, V33, P2475

[5] ORGANOMETALLIC CATALYSIS IN AQUEOUS-SOLUTION - OXYGEN-TRANSFER TO BROMIDE [J].

ESPENSON, JH ;

PESTOVSKY, O ;

HUSTON, P ;

STAUDT, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (07) :2869-2877

[6] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .122. METHYLTRIOXORHENIUM(VII) AS CATALYST FOR EPOXIDATIONS - STRUCTURE OF THE ACTIVE SPECIES AND MECHANISM OF CATALYSIS [J].

HERRMANN, WA ;

FISCHER, RW ;

SCHERER, W ;

RAUCH, MU .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1993, 32 (08) :1157-1160

[7] MULTIPLE BONDS BETWEEN MAIN-GROUP ELEMENTS AND TRANSITION-METALS .100. METHYLTRIOXORHENIUM AS CATALYST FOR OLEFIN OXIDATION [J].

HERRMANN, WA ;

FISCHER, RW ;

MARZ, DW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (12) :1638-1641

[8] METHYLTRIOXORHENIUM-CATALYZED OXIDATION OF A (THIOLATO)COBALT(III) COMPLEX BY HYDROGEN-PEROXIDE [J].

HUSTON, P ;

ESPENSON, JH ;

BAKAC, A .

INORGANIC CHEMISTRY, 1993, 32 (21) :4517-4523

[9] EQUILIBRIA AND KINETICS OF THE REACTIONS BETWEEN HYDROGEN-PEROXIDE AND METHYLTRIOXORHENIUM IN AQUEOUS PERCHLORIC-ACID SOLUTIONS [J].

YAMAZAKI, S ;

ESPENSON, JH ;

HUSTON, P .

INORGANIC CHEMISTRY, 1993, 32 (22) :4683-4687

[10] OXIDATION OF BENZALDEHYDES CATALYZED BY METHYLTRIOXORHENIUM WITH HYDROGEN-PEROXIDE [J].

YAMAZAKI, S .

CHEMISTRY LETTERS, 1995, (02) :127-128

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