DIRECT SYNTHESIS AND CRYSTAL-STRUCTURE OF LEAD(II) IODIDE COMPLEX WITH ETHANOLAMINE

被引：17

作者：

SKOPENKO, VV ^{[1
]}

KOKOZAY, VN ^{[1
]}

POLYAKOV, VR ^{[1
]}

SIENKIEWICZ, AV ^{[1
]}

机构：

[1] KIEV TG SHEVCHENKO STATE UNIV,DEPT CHEM,KIEV 252017,UKRAINE

来源：

POLYHEDRON | 1994年 / 13卷 / 01期

关键词：

D O I：

10.1016/S0277-5387(00)86631-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complex Pb-6(Ea)(6)(HEa)(2)I-6, (where HEa is ethanolamine) was obtained by interaction of lead oxide powder and ammonium iodide in ethanolamine. The crystal structure of the compound was determined by X-ray crystallography. The crystal is formed by [Pb-2(HEa)(2)(Ea)(2)](2+) and [Pb-4(Ea)(4)](4+) cations and iodide anions. Bidentate aminoethoxo groups are coordinated to lead via the oxygen and nitrogen atoms, whereas monodentate aminoethanol molecules are attached through the nitrogen atoms only.

引用

页码：15 / 18

页数：4

共 9 条

[1]

BATSANOV SS, 1991, ZH NEORG KHIM+, V36, P3015

[2]

HARRISON PC, 1987, COMPREHENSIVE COORDI

[3] CRYSTAL-STRUCTURE OF POLY[(TRIS-MU-IODO-BIS-LESS-THAN(2,2',2''-NITRILODIETHOXYETHANOL)DILEAD(II)GREATER-THAN)-MU-IODO] OBTAINED BY DIRECT-METHODS USING LEAD(II) OXIDE AS A STARTING MATERIAL [J].

KOKOZAY, V ;

SIENKIEWICZ, A .

POLYHEDRON, 1993, 12 (19) :2421-2423

[4]

KOKOZAY V, 1992, ZH NEORG KHIM, V37, P1642

[5]

KOKOZAY VN, 1992, J COORD CHEM A, V28, P191

[6]

PECHARSKII VK, 1984, VESTN VOV U K, V25, P9

[7]

SHELDRICK GM, 1986, SHELX PROGRAM CRYSTA

[8] AN EMPIRICAL-METHOD FOR CORRECTING DIFFRACTOMETER DATA FOR ABSORPTION EFFECTS [J].

WALKER, N ;

STUART, D .

ACTA CRYSTALLOGRAPHICA SECTION A, 1983, 39 (JAN) :158-166

[9]

Wells A.F., 1986, STRUCTURAL INORGANIC

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