PROTONATION OF THE AMINE NITROGENS IN EMERALDINE - EVIDENCE FROM X-RAY PHOTOELECTRON-SPECTROSCOPY

被引:39
作者
KANG, ET [1 ]
NEOH, KG [1 ]
TAN, KL [1 ]
TAN, BTG [1 ]
机构
[1] NATL UNIV SINGAPORE,DEPT PHYS,SINGAPORE 0511,SINGAPORE
关键词
EMERALDINE; PROTONATION; AMINE NITROGENS; NONVOLATILE ACIDS; XPS;
D O I
10.1016/0379-6779(92)90346-K
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The protonations of the emeraldine (EM) oxidation state of polyaniline (PAN) by non-volatile protonic acids, such as H2SO4 and HClO4, have been studied by X-ray photoelectron spectroscopy (XPS). The properly resolved N(1s) core-level spectra reveal that a large proportion of the amine nitrogens in the EM base powders and films is also susceptible to protonation when the samples are loaded with excessive non-volatile acids.
引用
收藏
页码:227 / 233
页数:7
相关论文
共 16 条
[1]   POLYANILINE - SOLUTIONS, FILMS AND OXIDATION-STATE [J].
ANGELOPOULOS, M ;
ASTURIAS, GE ;
ERMER, SP ;
RAY, A ;
SCHERR, EM ;
MACDIARMID, AG ;
AKHTAR, M ;
KISS, Z ;
EPSTEIN, AJ .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 160 :151-163
[2]   MULTIPLE LATTICE PHASES AND POLARON-LATTICE SPINLESS-DEFECT COMPETITION IN POLYANILINE [J].
JOZEFOWICZ, ME ;
LAVERSANNE, R ;
JAVADI, HHS ;
EPSTEIN, AJ ;
POUGET, JP ;
TANG, X ;
MACDIARMID, AG .
PHYSICAL REVIEW B, 1989, 39 (17) :12958-12961
[3]   STRUCTURAL DETERMINATION OF POLYANILINE BY X-RAY PHOTOELECTRON-SPECTROSCOPY [J].
KANG, ET ;
NEOH, KG ;
KHOR, SH ;
TAN, KL ;
TAN, BTG .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (11) :695-697
[4]   X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF POLYPYRROLE SYNTHESIZED WITH OXIDATIVE FE(III) SALTS [J].
KANG, ET ;
NEOH, KG ;
ONG, YK ;
TAN, KL ;
TAN, BTG .
MACROMOLECULES, 1991, 24 (10) :2822-2828
[5]   POLYANILINE - A NEW CONCEPT IN CONDUCTING POLYMERS [J].
MACDIARMID, AG ;
CHIANG, JC ;
RICHTER, AF ;
EPSTEIN, AJ .
SYNTHETIC METALS, 1987, 18 (1-3) :285-290
[6]   POLYANILINE - INTERCONVERSION OF METALLIC AND INSULATING FORMS [J].
MACDIARMID, AG ;
CHIANG, JC ;
HALPERN, M ;
HUANG, WS ;
MU, SL ;
SOMASIRI, NLD ;
WU, WQ ;
YANIGER, SI .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1985, 121 (1-4) :173-180
[7]  
MUILENBERG GE, 1977, HDB XRAY PHOTOELECTR, P58
[8]   SPECTROSCOPY AND TRANSIENT PHOTOCONDUCTIVITY OF PARTIALLY CRYSTALLINE POLYANILINE [J].
PHILLIPS, SD ;
YU, G ;
CAO, Y ;
HEEGER, AJ .
PHYSICAL REVIEW B, 1989, 39 (15) :10702-10707
[9]  
RAY A, 1989, SYNTHETIC MET, V29, pE141
[10]  
Skotheim T., 1986, HDB CONDUCTING POLYM, V1